{ "run_id": "DGTE-RHP-SYNTHESIS-20261020-R1", "verdict": "PASS_TARGETED_ARITHMETIC_AND_PROVENANCE_NOT_PHYSICAL_VALIDATION", "CoolProp": "8.0.0", "checks": [ { "name": "GPT_R1_numeric_sha", "passed": true }, { "name": "GPT_R1_post_sha", "passed": true }, { "name": "C1_PCM_eta_rounded", "passed": true }, { "name": "C1_PCM_dT_rounded", "passed": true }, { "name": "C1_saturation_height_Water", "passed": true }, { "name": "C1_saturation_height_R1233zd(E)", "passed": true }, { "name": "C1_saturation_height_R245fa", "passed": true }, { "name": "C1_saturation_height_Isopentane", "passed": true }, { "name": "C1_saturation_height_n-Pentane", "passed": true }, { "name": "C1_saturation_height_n-Hexane", "passed": true }, { "name": "C1_storage_conversion_only", "passed": true }, { "name": "C1_storage_35m_conversion_only", "passed": true }, { "name": "C1_pump_hydraulic_power", "passed": true }, { "name": "C1_pump_avoided_electric", "passed": true }, { "name": "C1_pump_to_turbine_ratio", "passed": true }, { "name": "NPV0_cost_per_net_kW", "passed": true }, { "name": "C1_lift_band_S60-F_0.2", "passed": true }, { "name": "C1_lift_band_S60-F_0.3", "passed": true }, { "name": "C1_lift_band_S60-F_0.36", "passed": true }, { "name": "C1_lift_band_S60-F_0.45", "passed": true }, { "name": "C1_lift_band_S60-F_0.55", "passed": true }, { "name": "C1_lift_band_S60-F_0.65", "passed": true }, { "name": "C1_lift_band_S90-F_0.2", "passed": true }, { "name": "C1_lift_band_S90-F_0.3", "passed": true }, { "name": "C1_lift_band_S90-F_0.36", "passed": true }, { "name": "C1_lift_band_S90-F_0.45", "passed": true }, { "name": "C1_lift_band_S90-F_0.55", "passed": true }, { "name": "C1_lift_band_S90-F_0.65", "passed": true }, { "name": "C1_own_S60_counterexample_positive", "passed": true }, { "name": "five_of_twelve_VL2_points_pass_necessary_screen_only", "passed": true } ], "PCM_C1_10m": { "eta_ideal_latent_only": 7.845319999999999e-05, "Clapeyron_shift_K": 0.026124915599999996 }, "pure_saturation_pressure_heights": [ { "fluid": "Water", "Th_C": 65, "Tc_C": 35, "carrier_rho_kg_m3": 985, "pure_vapor_pressure_span_height_m": 2.009677621655127, "scope": "Saturation-endpoint pressure equivalent; excludes carrier water vapor, losses, vacuum auxiliaries and a complete cycle." }, { "fluid": "R1233zd(E)", "Th_C": 65, "Tc_C": 35, "carrier_rho_kg_m3": 985, "pure_vapor_pressure_span_height_m": 27.426413386150497, "scope": "Saturation-endpoint pressure equivalent; excludes carrier water vapor, losses, vacuum auxiliaries and a complete cycle." }, { "fluid": "R245fa", "Th_C": 65, "Tc_C": 35, "carrier_rho_kg_m3": 985, "pure_vapor_pressure_span_height_m": 33.138416226269406, "scope": "Saturation-endpoint pressure equivalent; excludes carrier water vapor, losses, vacuum auxiliaries and a complete cycle." }, { "fluid": "Isopentane", "Th_C": 65, "Tc_C": 35, "carrier_rho_kg_m3": 985, "pure_vapor_pressure_span_height_m": 19.015125119323663, "scope": "Saturation-endpoint pressure equivalent; excludes carrier water vapor, losses, vacuum auxiliaries and a complete cycle." }, { "fluid": "n-Pentane", "Th_C": 65, "Tc_C": 35, "carrier_rho_kg_m3": 985, "pure_vapor_pressure_span_height_m": 15.48064188813931, "scope": "Saturation-endpoint pressure equivalent; excludes carrier water vapor, losses, vacuum auxiliaries and a complete cycle." }, { "fluid": "n-Hexane", "Th_C": 65, "Tc_C": 35, "carrier_rho_kg_m3": 985, "pure_vapor_pressure_span_height_m": 6.151280007932827, "scope": "Saturation-endpoint pressure equivalent; excludes carrier water vapor, losses, vacuum auxiliaries and a complete cycle." } ], "mixed_R1233_water_R4_65_35_head_m_rho990": 29.287423881503585, "storage": { "target_net_kW": 26.1, "hours": 16.0, "head_m": 5.45, "C1_conversion_only_m3": 35942.53828766923, "including_5kW_discharge_aux_m3": 42828.0820209392, "35m_conversion_only_m3": 5596.766676222781, "35m_with_5kW_aux_m3": 6668.94420040339 }, "pump": { "hydraulic_kW": 39.366364375799996, "flow_m3h": 2678.4, "head_m": 5.45, "avoided_pump_electric_kW_assuming_0p7_efficiency": 51.237663394, "turbine_net_kW": 26.119111039069896, "ratio": 1.9616924679158063, "scope": "One hydraulic duty, alternatives not additive. Export must preserve both mass/energy and pressure return balance." }, "C1_lift_band_recomputed": [ { "scenario": "S60-F", "gas_work_kW_assumed": 29.6, "lift_factor": 0.2, "net_kW": -0.3202399999999992 }, { "scenario": "S60-F", "gas_work_kW_assumed": 29.6, "lift_factor": 0.3, "net_kW": 2.0196400000000008 }, { "scenario": "S60-F", "gas_work_kW_assumed": 29.6, "lift_factor": 0.36, "net_kW": 3.4235679999999995 }, { "scenario": "S60-F", "gas_work_kW_assumed": 29.6, "lift_factor": 0.45, "net_kW": 5.52946 }, { "scenario": "S60-F", "gas_work_kW_assumed": 29.6, "lift_factor": 0.55, "net_kW": 7.869340000000001 }, { "scenario": "S60-F", "gas_work_kW_assumed": 29.6, "lift_factor": 0.65, "net_kW": 10.209220000000002 }, { "scenario": "S90-F", "gas_work_kW_assumed": 71.3, "lift_factor": 0.2, "net_kW": 6.27253 }, { "scenario": "S90-F", "gas_work_kW_assumed": 71.3, "lift_factor": 0.3, "net_kW": 11.908794999999998 }, { "scenario": "S90-F", "gas_work_kW_assumed": 71.3, "lift_factor": 0.36, "net_kW": 15.290554 }, { "scenario": "S90-F", "gas_work_kW_assumed": 71.3, "lift_factor": 0.45, "net_kW": 20.3631925 }, { "scenario": "S90-F", "gas_work_kW_assumed": 71.3, "lift_factor": 0.55, "net_kW": 25.999457500000002 }, { "scenario": "S90-F", "gas_work_kW_assumed": 71.3, "lift_factor": 0.65, "net_kW": 31.6357225 } ], "NPV0_EUR_per_net_kW": 6538.193661352781, "cost_dependent_lift_requirement": [ { "whole_installed_EUR_assumed": 100000, "required_net_kW": 15.294744264168761, "required_lift_at_C1_S90_gas_budget": 0.3600743446975748, "scope": "Conditional necessary NPV condition, fixed 5 kW auxiliary and C1 gas-work budget. No cost quotation." }, { "whole_installed_EUR_assumed": 170000, "required_net_kW": 26.001065249086892, "required_lift_at_C1_S90_gas_budget": 0.5500285250797629, "scope": "Conditional necessary NPV condition, fixed 5 kW auxiliary and C1 gas-work budget. No cost quotation." }, { "whole_installed_EUR_assumed": 200000, "required_net_kW": 30.589488528337522, "required_lift_at_C1_S90_gas_budget": 0.6314374595292721, "scope": "Conditional necessary NPV condition, fixed 5 kW auxiliary and C1 gas-work budget. No cost quotation." }, { "whole_installed_EUR_assumed": 450000, "required_net_kW": 68.82634918875942, "required_lift_at_C1_S90_gas_budget": 1.309845246608515, "scope": "Conditional necessary NPV condition, fixed 5 kW auxiliary and C1 gas-work budget. No cost quotation." } ], "selected_GPT_R1": { "Rankine_eta_expander_0p7": [ { "scenario": "S60-F", "Th_C": 44, "Tc_C": 36, "gross_electric_kW": 16.158929502666552, "feed_pump_electric_kW": 0.3714717709973406, "external_aux_kW_assumed": 5, "net_kW": 10.787457731669212 }, { "scenario": "S90-F", "Th_C": 64, "Tc_C": 36, "gross_electric_kW": 50.26174005926121, "feed_pump_electric_kW": 1.555951425091247, "external_aux_kW_assumed": 5, "net_kW": 43.70578863416996 } ], "VL2_necessary_screen_passes_only": [ { "scenario": "S60-F", "H": 10, "D": 0.8, "vgj": 0.25, "status": "CLAUDE_R4_SOURCE_WITH_NEW_CONTACT_TEMPERATURES", "carrier_dT_K": 0.7493676832810435, "remaining_carrier_to_gas_temperature_K": 0.25063231671895647, "thermal_budget_screen": "PASSES_NECESSARY_SCREEN_ONLY", "net_kW_eta0p85_aux5": 4.79521852441219 }, { "scenario": "S90-F", "H": 35, "D": 1.0, "vgj": 0.25, "status": "CLAUDE_R4_SOURCE_WITH_NEW_CONTACT_TEMPERATURES", "carrier_dT_K": 0.46323538480068455, "remaining_carrier_to_gas_temperature_K": 0.5367646151993155, "thermal_budget_screen": "PASSES_NECESSARY_SCREEN_ONLY", "net_kW_eta0p85_aux5": 25.706134171874677 }, { "scenario": "S90-F", "H": 35, "D": 1.0, "vgj": 0.5, "status": "CLAUDE_R4_SOURCE_WITH_NEW_CONTACT_TEMPERATURES", "carrier_dT_K": 0.6700755409829741, "remaining_carrier_to_gas_temperature_K": 0.32992445901702594, "thermal_budget_screen": "PASSES_NECESSARY_SCREEN_ONLY", "net_kW_eta0p85_aux5": 16.299211015084186 }, { "scenario": "S90-F", "H": 40, "D": 0.6, "vgj": 0.25, "status": "CLAUDE_R4_SOURCE_WITH_NEW_CONTACT_TEMPERATURES", "carrier_dT_K": 0.7416985815413429, "remaining_carrier_to_gas_temperature_K": 0.25830141845865706, "thermal_budget_screen": "PASSES_NECESSARY_SCREEN_ONLY", "net_kW_eta0p85_aux5": 26.32420285063254 }, { "scenario": "S90-F", "H": 40, "D": 0.6, "vgj": 0.5, "status": "CLAUDE_R4_SOURCE_WITH_NEW_CONTACT_TEMPERATURES", "carrier_dT_K": 0.8940157190683948, "remaining_carrier_to_gas_temperature_K": 0.10598428093160517, "thermal_budget_screen": "PASSES_NECESSARY_SCREEN_ONLY", "net_kW_eta0p85_aux5": 21.11140653551541 } ], "VP_R1233_ideal_cycle": [ { "status": "CLOSED_IDEAL_REAL_FLUID_PATH", "p_hot_Pa": 245025.06815533122, "p_cold_Pa": 189885.6841504819, "quality_after_isochoric_cooling": 0.7821840310785738, "W_J_kg": 4148.181574094529, "Qin_J_kg": 190677.5264839468, "Qout_J_kg": 186529.34490985237, "W_J_per_Lmax": 54.5526971877284, "Qin_J_per_Lmax": 2507.5983721986345, "W_return_compression_J_kg": -0.027082081469458785, "eta_ideal": 0.02175495796796885, "energy_residual_J_kg": -1.000444171950221e-10, "Sgen_J_kgK": 2.1400409140585452, "carnot": 0.02522465710231747, "scenario": "S60-F", "fluid": "R1233zd(E)", "Th_C": 44, "Tc_C": 36 }, { "status": "CLOSED_IDEAL_REAL_FLUID_PATH", "p_hot_Pa": 436748.6879250783, "p_cold_Pa": 189885.6841504819, "quality_after_isochoric_cooling": 0.44287418463270506, "W_J_kg": 10515.398973589447, "Qin_J_kg": 203932.23989983695, "Qout_J_kg": 193416.8409262477, "W_J_per_Lmax": 242.26269694096806, "Qin_J_per_Lmax": 4698.364232820209, "W_return_compression_J_kg": -0.17403479868070804, "eta_ideal": 0.051563200496175465, "energy_residual_J_kg": -2.0736479200422764e-10, "Sgen_J_kgK": 20.769812557903606, "carnot": 0.0830490879430521, "scenario": "S90-F", "fluid": "R1233zd(E)", "Th_C": 64, "Tc_C": 36 } ], "VP_S90_wall_sensitivity": [ { "scenario": "S90-F", "fluid": "R1233zd(E)", "wall_kg_per_Lmax_assumed": 0, "sensible_regen_assumed": 0, "wall_heat_J_per_Lmax": 0, "conditional_work_over_heat": 0.051563200496175465, "conditional_net_kW_if_full_1MW_input_maintained": 33.672400372131605, "not_a_rate_or_plant_model": true }, { "scenario": "S90-F", "fluid": "R1233zd(E)", "wall_kg_per_Lmax_assumed": 0, "sensible_regen_assumed": 0.8, "wall_heat_J_per_Lmax": 0.0, "conditional_work_over_heat": 0.051563200496175465, "conditional_net_kW_if_full_1MW_input_maintained": 33.672400372131605, "not_a_rate_or_plant_model": true }, { "scenario": "S90-F", "fluid": "R1233zd(E)", "wall_kg_per_Lmax_assumed": 0.1, "sensible_regen_assumed": 0, "wall_heat_J_per_Lmax": 1400.0, "conditional_work_over_heat": 0.039725849046069996, "conditional_net_kW_if_full_1MW_input_maintained": 24.794386784552497, "not_a_rate_or_plant_model": true }, { "scenario": "S90-F", "fluid": "R1233zd(E)", "wall_kg_per_Lmax_assumed": 0.1, "sensible_regen_assumed": 0.8, "wall_heat_J_per_Lmax": 279.99999999999994, "conditional_work_over_heat": 0.04866311214109939, "conditional_net_kW_if_full_1MW_input_maintained": 31.497334105824542, "not_a_rate_or_plant_model": true }, { "scenario": "S90-F", "fluid": "R1233zd(E)", "wall_kg_per_Lmax_assumed": 1, "sensible_regen_assumed": 0, "wall_heat_J_per_Lmax": 14000, "conditional_work_over_heat": 0.01295635778212822, "conditional_net_kW_if_full_1MW_input_maintained": 4.717268336596165, "not_a_rate_or_plant_model": true }, { "scenario": "S90-F", "fluid": "R1233zd(E)", "wall_kg_per_Lmax_assumed": 1, "sensible_regen_assumed": 0.8, "wall_heat_J_per_Lmax": 2799.9999999999995, "conditional_work_over_heat": 0.03230873953556277, "conditional_net_kW_if_full_1MW_input_maintained": 19.231554651672077, "not_a_rate_or_plant_model": true } ] }, "domains": { "Clapeyron": "Local equilibrium phase boundary: dT/dp=T*delta_v/L. Not a universal work/power bound for gas GC, NiTi/TCP or externally loaded stationary pressure cells.", "PCM_original": "For the stated single small-expansion gravity loop, W/m=rho*g*H*delta_v; dividing by required latent heat alone is an optimistic one-pass heat budget. Small positive work is not mathematical impossibility; it contradicts the original percent-efficiency target under these assumptions.", "lift_analog": "Compare liquid hydraulic power over isothermal gas expansion work at measured absolute endpoints. Meter compressor electricity separately. Match gas/liquid density ratio, geometry, submergence, flow/void regimes; air is not a full phase-change or NCG test.", "C1_Falsifier_missing_code": "C1 package contains a summary of 14/9 kW stacked-loss claims, but no fz.py-fz5.py code or detailed sweep results. Those values are reported sensitivities, not reproduced bounds.", "literature_absence": "Failure to retrieve matching high-efficiency data is not a measured upper bound or automatic rejection." }, "input_sha256": { "gpt/results/results.json": "9218abdd09427a284a4859395c5f9908413eab887233f9e6e75280f998319afe", "gpt/results/post_analysis.json": "e282d1e88d093a2e6dff5ce5fd5e6ef55353f66d54093e539a3c9d5c1b023a57", "claude_emp/emp2_modes_bounds.json": "fcb924edb907d19893b21b67f3beca82f88809ed6149fbfdd6403f129d32d606", "claude_emp/emp3_clapeyron_span.json": "c41a91b0400e65b9ce1411125d9d0f3d009faa5ef9ef444abbab33ae713b8c80", "claude_emp/emp4_lift_band.json": "5fbe9c5bd7b34ac0a8b9da2e1f8fcf0d253b043dba056b9f8b9bf07168b4874a" } }